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dc.creatorMardones, Lucas
dc.creatorLegnoverde, María Soledad
dc.creatorPereyra, Andrea
dc.creatorBasaldella, Elena
dc.date.accessioned2018-06-14T15:30:39Z
dc.date.available2018-06-14T15:30:39Z
dc.date.issued2017
dc.identifier.urihttp://hdl.handle.net/20.500.12272/2921
dc.description.abstractSilica mesoporous materials were proposed as new hosts for stabilizing isothiazolinone-based biocides. We synthesized two types of porous matrices: SBA-15 silica and mesocellular siliceous foam (MCF). The physicochemical properties of the silicas (structure, textural properties) are evaluated in order to determine their ability to encapsulate, stabilize and subsequently release, a commercial biocide used for latex preservation (CMIT/MIT). CMIT/MIT consists of an aqueous solution of the active ingredients CMIT (5-chloro-2-methyl-4-isothiazolin-3-one) and MIT (2-methyl-4-isothiazolin-3-one), present in a CMIT/MIT: 3/1 weight ratio. The two matrices were loaded with different biocide concentrations by using the traditional incipient wetness impregnation method. N2 adsorption, SEM and FTIR analyses showed that the biocide can be encapsulated within silica frameworks and preserved its original structure. Release tests in aqueous media indicated that the CMIT/MIT concentration in the leaching solution depends on the matrix nature, being the smaller values obtained when ordered matrices were used. Desorption experiments indicated that the biocide delivery in aqueous media could be delayed by increasing the pH of test solutions. Results showed that biocide encapsulation allows maintaining a long-lasting release, preserving the biocide activity even under conditions of temperature and pH at which decomposition and hydrolysis of non-supported CMIT is observed.es_ES
dc.formatapplication/pdf
dc.language.isoenges_ES
dc.publisherInternational Colloids Conferencees_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectStudy of loading, isothiazolinone based biocide, release profiles, mesoporous silica matriceses_ES
dc.titleStudy of loading isothiazolinone based biocide and release profiles from mesoporous silica matriceses_ES
dc.typeinfo:eu-repo/semantics/conferenceObjectes_ES
dc.description.affiliationFil: Mardones, Lucas. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentinaes_ES
dc.description.affiliationFil: Legnoverde, María Soledad. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentinaes_ES
dc.description.affiliationFil: Pereyra, Andrea. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentinaes_ES
dc.description.affiliationFil: Basaldella, Elena. UTN (Universidad Tecnológica Nacional). CITEMA (Centro de Investigación y Desarrollo en Ciencia y Tecnología de Materiales). UNLP (Universidad Nacional La Plata). CINDECA; Argentinaes_ES
dc.description.peerreviewedPeer Reviewedes_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersiones_ES
dc.type.snrddocunento de conferenciaes_ES
dc.rights.useAtribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.).es_ES


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