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dc.creatorRivoira, Lorena Paola
dc.creatorLedesma, Brenda Cecilia
dc.creatorGómez Costa, Marcos Bruno
dc.creatorBeltramone, Andrea Raquel
dc.date.accessioned2024-04-15T23:32:52Z
dc.date.available2024-04-15T23:32:52Z
dc.date.issued2020
dc.identifier.urihttp://hdl.handle.net/20.500.12272/10530
dc.description.abstractA clean energy revolution is taking place all over the world in pursuit of replacing oil. This work stands out an environmental point of view by proposing biomass wastes from different industrial areas to produce not only a biofuel but also as raw material to synthetize the catalyst involved in the HDO reaction. In this way the process ceases to rely on the antiquated and obsolete linear economy where products, services, wastes, materials, water and energy have a beginning and an end to become a process with greater tendency to the modern circular economy, closely related to the idea of sustainability. Products, materials and resources are expected to last as long as possible while minimizing waste as much as possible too. Agricultural and forestry waste are available everywhere being a low cost raw material and it is possible to provide added value to the organic wastes of small and medium size enterprises. The hydrodeoxygenation (HDO) of guaiacol has been performed in a batch reactor under 12 atm of H2 and different temperatures over activated carbon synthetized from orange peel discarded from juice industry. Carbon activation was carried out through a chemical process with phosphoric acid as an activating agent, varying the acid concentration, the ratio substrate/activating agent and time of contact between them. The best support was obtained using carbonization time of 1 h, temperature of carbonization of 470oC, phosphoric acid concentration of 50 wt.% and with BET area of 1429 m2/g. Subsequently, the metallic nanoparticles were deposited in the activated carbon to use the solid as a catalytic material for the hydrodeoxygenation of guaiacol. The catalytic material was modified with metallic nanoparticles of Pt. The catalysts were characterized by means of X-ray diffraction, N2 isotherms, XPS, SEM and TEM. Good structure, narrow pore size distribution and high platinum dispersion were achieved in the synthesized catalysts. The objective of this investigation is the evaluation of the catalytic activity and to compare it with SBA-15 support studied previously. The catalyst presented excellent performance for biofuels generation.es_ES
dc.formatpdfes_ES
dc.language.isoenges_ES
dc.language.isoenges_ES
dc.rightsopenAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.rights.uriAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.subjectbiofueles_ES
dc.subjectbiomasses_ES
dc.subjectHDOes_ES
dc.titleNew catalyst source applied in biofuel manufacturinges_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderBeltramone, Andrea Raqueles_ES
dc.description.affiliationFil: Rivoira, Lorena. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.es_ES
dc.description.affiliationFil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.es_ES
dc.description.affiliationFil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.es_ES
dc.description.affiliationFil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.es_ES
dc.description.peerreviewedPeer Reviewedes_ES
dc.type.versionpublisherVersiones_ES
dc.rights.usehttps://creativecommons.org/licenses/by-nc-sa/4.0/es_ES
dc.identifier.doi-


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