Facultad Regional Córdoba

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    Funcionalización de α–pineno con catalizadores mesoporosos modificados con Cobre y un oxidante verde. optimización de las condiciones de reacción
    (2013) Cánepa, Analía Laura; Eimer, Griselda Alejandra; Casuscelli, Sandra Graciela
    In this work we report the α-pinene oxidative functionalization using mesoporous materials as a heterogeneous catalyst modified with Cu and hydrogen peroxide as oxidant. The reaction conditions were optimized by performing an addition of hydrogen peroxide at 0.5 h of reaction. Thus, the α-pinene conversion was closed to 23% being verbenone the major product. Moreover, the stability of the catalyst to the leaching of the active species and the possibility of recycling were checked. The results confirm that the Cu species are not leached during the reaction. Thus heterogeneous catalyst can be recovered and reused many times without loss in catalytic activity and selectivity.