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    Hydrogenation of tetralin over Ir catalysts supported on titania-modified SBA-16
    (2014) Ledesma, Brenda; Vallés, Verónica; Rivoira, Lorena Paola; Martínez, María Laura; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel
    Abstract A series of Ti modified SBA-16 supports and their respective Ir-catalysts were prepared and character- ized to study the effect of support preparation method on the dispersion of iridium and on the characteristics of Ir surface species. Two methods of incorporation of titania were tested: the sol–gel method in order to obtain Ti as heteroatom and incipient wetness impregnation to obtain Ti as TiO2 (anatase phase). The results show that supports with different Ti species and dispersion can be obtained. The final catalyst was characterized at different preparation stages by XRD, elemental analysis and BET. The presence of Ti as Ti4? in the nanostructure of SBA and as TiO2 (anatase phase) was analyzed by UV–Vis–DRS and Raman spectroscopy. The iridium oxidation sate upon Ti-con- taining SBA-16 was studied by XPS, EDX, TEM and XRD, arriving at the good proportion of Ir0. H2 chemi- sorption and TEM characterization for Ti-SBA-16 indi- cated that Ir particle size was lower than anatase/SBA-16. The catalyst that we synthesized had good activity mea- sured in tetralin hydrogenation in presence of quinoline at mild conditions. The experimental data were quantitatively represented by a modified Langmuir–Hinshelwood-type rate equation. The preliminary results show these materials as promising catalysts for HDS/HDN reactions.
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    Syntesis, characterization and hydrotreating catalitic performance of Ir/Ti-SBA-16 and Ir/TIO2-SBA-16.
    (2014) Ledesma, Brenda; Vallés, Verónica; Rivoira, Lorena Paola; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel
    A series of Ti modified SBA-16 supports and their respective Ir-catalysts were prepared, and characterized to study the effect of support preparation method on the dispersion of iridium and on the characteristics of Ir surface species, with the main aim of obtaining Nitrogen-tolerant catalysts to be used in second stage processes of mild-hydrotreating. Two methods of titania incorporation were tested: the sol-gel method in order to obtain Ti as heteroatom and incipient wetness impregnation to obtain Ti as TiO2 (anatase phase). The final catalyst was characterized at different stage of preparation by XRD, EDX, TEM, elemental analysis and BET, arriving at the good proportion of Ir0. The presence of Ti as Ti+4 in the nanostructure of SBA and as TiO2 (anatase phase) was analyzed by UV-vis-DRS and Raman spectroscopy. The average metal particle size indicates that the Ir particle size is lower when we used Ti-SBA-16 than anatase/SBA-16. We study the catalytic properties of 1 wt% Ir-containing SBA-16 materials modified with Ti as heteroatom and impregnated with TiO2 (anatase phase), in the hydrogenation of tetralin to decalin in the presence of 100 ppm of N as quinoline at 250°C and 15 atm of pressure of hydrogen, using a Parr reactor. The catalysts synthesized by us had good activity measured in tetralin hydrogenation under mild conditions. The experimental data was quantitatively represented by a modified Langmuir-Hinshelwood type rate equation. The preliminary results show these materials as promising catalysts for HDT and HDN reactions.
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    Synthesis, characterization and hydrotreating activity of Ir catalysts supported on titania-modified mesoporous material
    (2014) Ledesma, Brenda; Vallés, Verónica; Rivoira, Lorena Paola; Martínez, María Laura; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel
    A titanium modified catalyst based on noble metal has been prepared with the main aim of obtaining Nitrogen-tolerant catalysts to be used in second stage processes of mild-hydrotreating. We study the catalytic properties of 1 wt% Ir-containing SBA-16 materials modified with Ti as heteroatom and impregnated with TiO2 (anatase phase), in the hydrogenation of tetralin to decalin in the presence of 100 ppm of N as quinoline at 250°C and 15 atm of pressure of hydrogen, using a Parr reactor. The iridium oxidation sate upon Ti-containing SBA-16 was studied by XPS, EDX, TEM and XRD, arriving at the good proportion of Ir0. The average metal particle size indicate that the Ir particle size is lower when we used Ti-SBA-16 than anatase/SBA-16. The experimental data was quantitatively represented by a modified Langmuir-Hinshelwood type rate equation. The preliminary results show these materials as promising catalysts for HDS/HDN reactions.