FRVT - Artículos en Revistas Internacionales
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Item Ambient Species Density and Gas Temperature Radial Profiles Derived from a Schlieren Technique in a Low Frequency Non-thermal Oxygen Plasma Jet.(2017) Chamorro, Juan Camilo; Prevosto, Leandro; Cejas, Ezequiel; Kelly, Héctor; Mancinelli, Beatriz; Fischfeld, GerardoA quantitative interpretation of the schlieren technique applied to a non-thermal atmospheric-pressure oxygen plasma jet driven at low-frequency (50 Hz) is reported. The jet was operated in the turbulent regime with a hole-diameter based Reynolds number of 13,800. The technique coupled to a simplified kinetic model of the jet effluent region allowed deriving the temporally-averaged values of the gas temperature of the jet by processing the gray-level contrast values of digital schlieren images. The penetration of the ambient air into the jet due to turbulent diffusion was taken into account. The calibration of the optical system was obtained by fitting the sensitivity parameter so that the oxygen fraction at the nozzle exit was unity. The radial profiles of the contrast in the discharge off case were quite symmetric on the whole outflow, but with the discharge on, relatively strong departures from the symmetry were evident in the near field. The time-averaged gas temperature of the jet was relatively high, with a maximum departure of about 55 K from the room temperature; as can be expected owing to the operating molecular gas. The uncertainty in the temperature measurements was within 6 K, primarily derived from errors associated to the Abel inversion procedure. The results showed an increase in the gas temperature of about 8 K close to the nozzle exit; thus suggesting that some fast-gas heating (with a heating rate *0.3 K/ls) still occurs in the near field of the outflow.Item An Interpretation of Langmuir Probe Floating Voltage Signals in a Cutting Arc.(2009) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizAn experimental study of the electrostatic probe floating voltage signals in a cutting arc and its physical interpre tation in terms of the arc plasma structure is reported. Sweeping electrostatic probes have been used to register the local floating potential and ion current at 3.5 mm from the nozzle exit in a 30-A arc generated by a high energy density cutting torch with a nozzle bore radius of 0.5 mm and an oxygen mass flow rate of 0.71 g · s−1. It is found that the floating potential signal presented a central hump with duration almost similar to that corresponding to the ion current signal but having also lateral wings with much larger duration. Capacitive coupling between the probe and the conducting body of the nozzle and arc as a source for the float ing potential signal was discarded. It is assumed that the hump in these probe voltage signals results from the presence of an electrostatic field directed in the radial direction outward the arc axis that is caused by thermoelectric effects. The probe floating voltage signal is inverted using the generalized Ohm’s law together with the Saha equation, thus obtaining the radial profiles of the temperature, particle densities, radial electric field, and potential of the plasma at the studied section of the arc. The resulting temperature and density profiles derived from our interpretation are in good agreement with the data published elsewhere in this kind of high-pressure arcs. There is not a straightforward connec tion between the measured hump amplitude in the floating signal (≈4 V) and the derived increase in the plasma potential between the arc edge and the arc center (≈10 V), due to the global zero cur rent balance condition established by the finite size of the probe. It is shown, however, that the probe takes a floating potential value close to that corresponding to the plasma temperature at the probe center.Item Correlation methods in cutting arcs(IOPscience, 2011-05-25) Prevosto, Leandro; Kelly, HéctorThe present work applies similarity theory to the plasma emanating from transferred arc, gas-vortex stabilized plasma cutting torches, to analyze the existing correlation between the arc temperature and the physical parameters of such torches. It has been found that the enthalpy number significantly influence the temperature of the electric arc. The obtained correlation shows an average deviation of 3 % from the temperature data points. Such correlation can be used, for instance, to predict changes in the peak value of the arc temperature at the nozzle exit of a geometrically similar cutting torch due to changes in its operation parameters.Item Departures from local thermodynamic equilibrium in cutting arc plasmas derived from electron and gas density measurements using a twowavelength quantitative Schlieren technique.(2011) Prevosto, Leandro; Artana, Guillermo; Kelly, Héctor; Mancinelli, BeatrizA two-wavelength quantitative Schlieren technique that allows inferring the electron and gas densities of axisymmetric arc plasmas without imposing any assumption regarding statistical equilibrium models is reported. This technique was applied to the study of local thermodynamic equilibrium (LTE) departures within the core of a 30 A high-energy density cutting arc. In order to derive the electron and heavy particle temperatures from the inferred density profiles, a generalized two-temperature Saha equation together with the plasma equation of state and the quasineutrality condition were employed. Factors such as arc fluctuations that influence the accuracy of the measurements and the validity of the assumptions used to derive the plasma species temperature were considered. Significant deviations from chemical equilibrium as well as kinetic equilibrium were found at elevated electron temperatures and gas densities toward the arc core edge. An electron temperature profile nearly constant through the arc core with a value of about 14 000–15 000 K, well decoupled from the heavy particle temperature of about 1500 K at the arc core edge, was inferred.Item Determination of plasma velocity from light fluctuations in a cutting torch.(2009) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizItem Diagnostics of cutting arc plasmas.(2014) Prevosto, Leandro; Kelly, HéctorAn over-view of several remote and invasive diagnostics to characterize cutting arcs at the nozzle exit-anode gap as well as inside the nozzle is reported. A briefly description of the experimental set-ups, together with the main results obtained in a 30 A high-energy density cutting torch (including the calculation assumptions) are given.Item Effects of non–thermal plasmas on seed-borne Diaporthe/Phomopsis complex and germination parameters of soybean seeds.(2018) Pérez Pizá, María Cecilia; Prevosto, Leandro; Zilli, Carla; Cejas, Ezequiel; Kelly, Héctor; Balestrasse, KarinaDiaporthe/Phomopsis (D/P) is a complex of seed-borne fungi that severely affects soybean (Glycine max (L.) Merrill), one of the most important crops worldwide. Non-thermal plasma treatment is a fast, economic and ecological friendly technology that can destroy seed-borne fungi and improve seed quality. Soybean seeds were exposed for 1, 2 and 3 minutes to a quasi-stationary (50 Hz) dielectric barrier discharge plasma operating at atmospheric pressure air. Different carrying gases (O2 and N2) and barrier-insulating materials were used. In this work we focused on the ability of plasma to control D/P in soybean seeds and to enhance seed quality. To support these results, different antioxidant enzymes (catalase, superoxide dismutase and guaiacol peroxidase), lipid peroxidation and phytohormones (ABA and AIA) content in seeds were evaluated. The results demonstrated reductions of 29% in catalase activity and increments of 30% in glutathione content after plasma treatment, reversing the oxidative damage caused by D/P fungi. This eco-friendly technology improved soybean seed quality and, for the first time, its efficiency in controlling soybean seed-borne pathogen fungi that colonize the inside of seeds was demonstrated.Item Experimental Characterization of a Low-Current Cutting Torch.(2004) Kelly, Héctor; Mancinelli, Beatriz; Prevosto, Leandro; Minotti, Fernando; Márquez, AndrésAn experimental characterization of a low-current (30-40 A) cutting torch is presented. To avoid contamination of the plasma arc by removed anode material, a rotating steel cylinder was used as the anode and the arc was anchored onto the cylinder lateral surface. The cathode-anode and cathode-nozzle voltage drops, together with the gas pressure in the plenum chamber were registered for different values of the mass flow rate injected into the plenum chamber. By employing an optical system with a large magnification (≈ 15 X), the arc radius at the nozzle exit was also determined with a digital optical camera. The obtained experimental quantities were used to evaluate several flow properties at the nozzle exit (hot arc plasma and cold gas temperatures, arc and gas velocities, etc.) by employing a simplified theoretical model for the plasma flow in the nozzle. The obtained results are in reasonable agreement with the data reported in the literature by other authors. Explanations of the origin of the clogging effect and the nozzle voltage are also presented.Item Hydrodynamic Model for the Plasma-Gas Flow in a Cutting Torch Nozzle.(2004) Kelly, Héctor; Minotti, Fernando; Prevosto, Leandro; Mancinelli, BeatrizWe present a simple hydrodynamic model to obtain the profiles of the relevant physical quantities along a nozzle of arbitrary cross-section in a cutting torch. The model uses a two-zone approximation (a hot central plasma carrying the discharge current wrapped by a relatively cold gas which thermally isolates the nozzle wall from the plasma). Seeking for a solution with sonic conditions at the nozzle exit, the model allows expressing all the profiles in terms of the externally controlled parameters of the torch (geometry of the torch, discharge current, mass flow of the gas and plenum pressure) and the values of the arc and gas temperatures at the nozzle entrance. These last two values can be estimated simply appealing to energy conservation in the cathode-nozzle region. The model contains additional features compared with previous reported models, while retaining simplicity. The detailed consideration of an arc region coupled to the surrounding gas dynamics allows determining voltage drops and consequent delivered power with less assumptions than those found in other published works, and at the same time reduces the set of parameters needed to determine the solution.Item Interpretation of Voltage Measurements in Cutting Torches.(2015) Prevosto, Leandro; Kelly, Héctor; Minotti, Fernando Oscar; Mancinelli, BeatrizAnode-cathode and nozzle-cathode voltages, plenum pressure and gas mass flow measurements in a low current (30 A) cutting torch, operated with oxygen gas, are used as inputs for an electrical model coupled to a simplified fluid model, in order to infer some properties of the plasma-gas structure that are difficult to measure.Item Investigation of the relevant kinetic processes in the initial stage of a double-arcing instability in oxygen plasmas.(2018) Mancinelli, Beatriz; Prevosto, Leandro; Chamorro, Juan Camilo; Minotti, Fernando; Kelly, HéctorA numerical investigation of the kinetic processes in the initial (nanosecond range) stage of the double-arcing instability was developed. The plasma-sheath boundary region of an oxygen operated cutting torch was considered. The energy balance and chemistry processes in the dis charge were described. It is shown that the double-arcing instability is a sudden transition from a diffuse (glow-like) discharge to a constricted (arc-like) discharge in the plasma-sheath boundary region arising from a field-emission instability. A critical electric field value of 107 V/m was found at the cathodic part of the nozzle wall under the conditions considered. The field-emission instability drives in turn a fast electronic-to-translational energy relaxation mechanism, giving rise to a very fast gas heating rate of at least 109 K/s, mainly due to reactions of preliminary dissocia tion of oxygen molecules via the highly excited electronic state populated by electron impact. It is expected that this fast oxygen heating rate further stimulates the discharge contraction through the thermal instability mechanism.Item Langmuir probe diagnostics of an atmospheric pressure, vortex–stabilized nitrogen plasma jet(2012-09-19) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizLangmuir probe measurements in an atmospheric pressure direct current (dc) plasma jet are reported. Sweeping probes were used. The experiment was carried out using a dc non–transferred arc torch with a rod–type cathode and an anode of 5mm diameter. The torch was operated at a nominal power level of 15kW with a nitrogen flow rate of 25 Nl min 1. A flat ion saturation region was found in the current–voltage curve of the probe. The ion saturation current to a cylindrical probe in a high–pressure non local thermal equilibrium (LTE) plasma was modeled. Thermal effects and ionization/recombination processes inside the probe perturbed region were taken into account. Averaged radial profiles of the electron and heavy particle temperatures as well as the electron density were obtained. An electron temperature around 11 000 K, a heavy particle temperature around 9500K and an electron density of about 4 1022m 3, were found at the jet centre at 3.5mm downstream from the torch exit. Large deviations from kinetic equilibrium were found throughout the plasma jet. The electron and heavy particle temperature profiles showed good agreement with those reported in the literature by using spectroscopic techniques. It was also found that the temperature radial profile based on LTE was very close to that of the electrons. The calculations have shown that this method is particularly useful for studying spraying–type plasma jets characterized by electron temperatures in the range 9000–14 000 K. VC 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4752886]Item Langmuir probe measurements in a time-fluctuating-highly ionized non-equilibrium cutting arc: Analysis of the electron retarding part of the time-averaged current-voltage characteristic of the probe.(2013) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizThis work describes the application of Langmuir probe diagnostics to the measurement of the electron temperature in a time-fluctuating-highly ionized, non-equilibrium cutting arc. The electron retarding part of the time-averaged current-voltage characteristic of the probe was analysed, assuming that the standard exponential expression describing the electron current to the probe in collision-free plas mas can be applied under the investigated conditions. A procedure is described which allows the determination of the errors introduced in time-averaged probe data due to small-amplitude plasma fluctuations. It was found that the experimental points can be gathered into two well defined groups allowing defining two quite different averaged electron temperature values. In the low-current re gion the averaged characteristic was not significantly disturbed by the fluctuations and can reliably be used to obtain the actual value of the averaged electron temperature. In particular, an averaged electron temperature of 0.98 ± 0.07 eV (= 11400 ± 800 K) was found for the central core of the arc (30 A) at 3.5 mm downstream from the nozzle exit. This average included not only a time-average over the time fluctuations but also a spatial-average along the probe collecting length. The fitting of the high-current region of the characteristic using such electron temperature value together with the corrections given by the fluctuation analysis showed a relevant departure of local thermal equilibrium in the arc core.Item Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes.(2016) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizA model of an atmospheric pressure nitrogen glow discharge in high-gas tem perature regimes is developed. The model considers a fairly complete set of chemical reactions, including several processes with the participation of electronically exited nitrogen atoms describing the energy balance and charged particles kinetic processes in the dis charge. It is shown that the thermal dissociation of vibrationally excited molecules plays an essential role in the production of N(4 S) atoms. The dominant ion within the investigated current range (52–187 mA) is the molecular N2 ? with an increasing proportion of atomic N? towards high-current values. The process of production of electrons within the almost whole current range is controlled predominantly by associative ionization in atomic colli sions N(2 P) ? N(2 P) ? N2 ? ? e; being the N(2 P) atoms mainly produced via quenching of N2(A3Pu ?) electronically excited molecules by N(4 S) atoms. The results of calculations are compared with the available experimental data and a good agreement is found.Item Modelling of the Plasma–Sheath Boundary Region in Wall-Stabilized Arc Plasmas: Unipolar Discharge Properties.(2017) Mancinelli, Beatriz; Prevosto, Leandro; Chamorro, Juan Camilo; Minotti, Fernando; Kelly, HéctorA two-dimensional model of the non-equilibrium unipolar discharge occurring in the plasma–sheath boundary region of a transferred-arc was developed. This model was used to study the current transfer to the nozzle (1 mm diameter) of a 30 A arc cutting torch operated with oxygen. The energy balance and chemistry processes in the discharge were described by using a kinetic block of 45 elementary reactions and processes with the participation of 13 species including electronically excited particles. The nonlocal transport of electrons was accounted for into the fluid model. The dependence of the ion mobility with the electric field was also considered. Basic discharge properties were described. It has been found that a large part (* 80%) of the total electric power (1700 mW) delivered in the bulk of the sheath region is spent in heating the positive ions and further dissipated through collisions with the neutral particles. The results also showed that the electron energy loss in inelastic collisions represents only * 25% of the electron power and that about 63% of the power spent on gas heating is produced by the ion– molecule reaction, the electron–ion and ion–ion recombination reactions, and by the electron attachment. The rest of the power converted into heat is contributed by dissociation by electron-impact, dissociative ionization and quenching of O(1 D). Some fast gas heating channels which are expected to play a key role in the double-arcing phenomena in oxygen gas were also identified.Item Numerical investigation of the double-arcing phenomenon in a cutting arc torch.(2014) Mancinelli, Beatriz; Minotti, Fernando; Prevosto, Leandro; Kelly, HéctorA numerical investigation of the double-arcing phenomenon in a cutting arc torch is reported. The dynamics of the double-arcing were simulated by using a two-dimensional model of the gas breakdown development in the space-charge layer contiguous to the nozzle of a cutting arc torch operated with oxygen. The kinetic scheme includes ionization of heavy particles by electron impact, electron attachment, electron detachment, electron–ion recombination, and ion–ion recombination. Complementary measurements during double-arcing phenomena were also conducted. A marked rise of the nozzle voltage was found. The numerical results showed that the dynamics of a cathode spot at the exit of the nozzle inner surface play a key role in the raising of the nozzle voltage, which in turn allows more electrons to return to the wall at the nozzle inlet. The return flow of electrons thus closes the current loop of the double-arcing. The increase in the (floating) nozzle voltage is due to the fact that the increased electron emission at the spot is mainly compensated by the displacement current (the ions do not play a relevant role due to its low-mobility) until that the stationary state is achieved and the electron return flow fully-compensates the electron emission at the spot. A fairly good agreement was found between the model and the experiment for a spot emission current growth rate of the order of 7 x 104 A/s.Item On the dynamic behavior of the anode–arc–root at the nozzle surface in a non-transferred plasma torch(2012) Prevosto, Leandro; Risso, Marcelo Natalio; Infante, Damián Leandro; Cejas, Ezequiel; Kelly, Héctor; Mancinelli, BeatrizThe dynamic behavior of the anode–arc–root at the nozzle surface of a plasma torch was experimentally investigated in this work. A gas (N2) vortex–stabilized non–transferred arc torch with a thoriated tungsten rod (2wt %) cathode (3.2 mm diameter) and a coaxial anode (5 mm diameter, 30 mm length) was used in the experiment. By using a sweeping Langmuir probe in floating condition, the voltage of the plasma jet outside the nozzle was inferred. Arc voltage waveforms were also obtained. Data have been obtained for an arc current of 100 A and a gas flow rate of 30 Nl min-1. A typical sawtooth shape (i.e., restrike mode) (with a fluctuating level of º 25 %) and a dominant frequency of º 6.5 kHz was observed in the arc voltage waveforms, which is attributed to anode–arc–root movements along the anode surface followed by a restrike at a certain point close to the cathode. By performing a time correlation between the probe and arc voltage oscillograms together with simple estimations, the amplitude of the movement of the arc–root along the anode surface as well its velocity were inferred.Item On the dynamics of cutting arc plasmas: the role of the power supply ripple(ADVANCED ELECTROMAGNETICS, 2012-08) Prevosto, Leandro; Mancinelli, Beatriz; Kelly, HéctorThe power sources used in cutting arc torches are usually poorly stabilized and have a large ripple factor. The strong oscillatory components in the voltage and arc current produce in turn, large fluctuations in the plasma quantities. Experimental observations on the dynamics of the nonequilibrium plasma inside the nozzle of a 30 A oxygen cutting torch with a 7 % ripple level of its power source are reported in this work. The observed electron temperature (mean value º 5400 K) shows a rms deviation º 5 % (≤ 300 K), which is of the order of the arc voltage ripple level. A considerable different situation occurs with the plasma density (mean value º 3 ´ 1019 m-3). In this case the rms deviation was º 75 %, much greater than that of the electron temperature.Item On the dynamics of the space-charge layer inside the nozzle of a cutting torch and its relation with the “non-destructive” double-arcing phenomenon(2011) Prevosto, Leandro; Kelly, Héctor; Mancinelli, BeatrizExperimental observations on the plasma dynamics inside the nozzle of a 30 A oxygen cutting torch operated at conditions close to the double arcing are reported. It is employed a technique previously developed in our laboratory consisting in using the nozzle as a large-sized Langmuir probe. Based on the behavior of the ion current signal and simple estimations, it is concluded that (1) the non-equilibrium plasma inside the nozzle is far from the steady state in time, in contrast to what is frequently assumed. The power supply ripple was identified as the main fluctuations source and (2) large-scale plasma fluctuations inside the nozzle could cause transient (total duration of the order of 100 ls) Townsend avalanches developing in the space-charge layer located between the arc plasma and the nozzle wall. Such events trigger the so called non-destructive double-arcing phenomena without appealing to the presence of insulating films deposited inside the nozzle orifice, as was previously proposed in the literature.Item On the Gas Heating Mechanism for the Fast Anode Arc Reattachment in a Non-transferred Arc Plasma Torch Operating with Nitrogen Gas in the Restrike Mode.(2015) Prevosto, Leandro; Kelly, Héctor; Mancinelli, Beatriz; Chamorro, Juan CamiloThe present work provides a detailed kinetic analysis of the time-resolved dynamics of the gas heating during the arc reattachment in nitrogen gas in order to understand the main processes leading to such a fast reattachment. The model includes gas heating due to the relaxation of the energy stored in the vibrational as well as the electronic modes of the molecules. The results show that the anode arc reattachment is essentiality a threshold process, corresponding to a reduced electric field value of E/N * 40 Td for the plasma discharge conditions considered in this work. The arc reattachment is triggered by a vibrational instability whose development requires a time of the order of 100 ls. For E/N\80–100 Td, most of the electron energy is transferred to gas heating through the mechanism of vibrational–translational relaxation. For larger values of E/N the electronic– translational energy relaxation mechanism produces a further intensification of the gas heating. The sharp increase of the gas heating rate during the last few ls of the vibrational instability give rises to a sudden transition from a diffuse (glow-like) discharge to a constricted arc with a high current density (*107 A/m2 ). This sudden increase in the current density gives rise to a new anode attachment closer to the cathode (where the voltage drop between the original arc and the anode is the largest) thus causing the decay of the old arc spot.