UTN- FRC -Producción Académica de Investigación y Desarrollo

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Subject: search.filters.subject.Iridium

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Now showing 1 - 5 of 5
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    Noble-biometallic supported CMK-3 as a novel catalyst for hydrogenation of tetralin in the presence of sulfur and nitrogen.
    (Universidad Tecnológica Nacional Regional Córdoba., 2017) Vallés, Verónica Alejandra; Ledesma , Brenda Cecilia; Juárez, Juliana María; Gómez costa , Marcos Bruno; Anunziata, Oscar Alfredo; Beltramone , Andrea Raquel; Gómez costa , Marcos; Ledesma , Brenda
    Carbon ordered mesoporous CMK-3 with high surface area and high pore volume promotes a very good dispersion of Pt or Ir monometallic and Pt-Ir-bimetallic crystallites in the carbon framework. High active and stable nanospecies are responsible for the good activity and selectivity found in the hydrogenation of tetralin to decalin in the presence of N as indole and S as dibenzothiophene under mild conditions in a Batch reactor. The catalysts prepared were extensively characterized by XRD, N2 adsorption isotherms, XPS, TEM, ICP, CO Chemisorption and TPR. The analysis showed that the carbon mesoporous structure was maintained after metal incorporation, and very high dispersed metal-supported catalyst was obtained. The activity was compared using the turnover number, Pt-Ir-CMK-3 being the most active cat alyst in the presence of the inhibitors. The bimetallic catalyst showed more resistance to inhibition than monometallic catalysts. The reusability of Pt-Ir-CMK-3 suggests that it is a potential catalyst for hydrotreating reactions.
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    Influence of Ti Incorporationto Bimetallic Mesoporous Carbon in the Production of 2,5-Dimethylfuran from Biomass Derivatives.
    (Universidad Tecnológica Nacional., 2021) Ledesma , Brenda Cecilia; Juárez , Juliana María; Domine , Marcelo; Beltramone, Andrea Raquel; Beltramone, Andrea Raquel; Juárez , Juliana María
    Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done to understand structure–activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetal lic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
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    Bimetallic platinum/iridium modified mesoporous catalysts applied in the hydrogenation of HMF.
    (Universidad Tecnológica Nacional., 2021) Ledesma , Brenda Cecilia; Juárez , Juliana María; Mazario , Jaime; Domine, Marcelo; Beltramone , Andrea Raquel; Juárez , Juliana María
    Catalytic transformation of 5-hydroxymethylfurfural (HMF) to produce 2,5-dimethylfuran (2,5-DMF) was stu- died over bimetallic (PtIr) and monometallic (Pt) catalysts supported on CMK-3 and SBA-15 mesoporous ma- terials. The optimum temperature and hydrogen pressure for the maximum production of 2,5-DMF were 120 °C and 15 atm, respectively. Increases in temperature and pressure decreased the selectivity to 2,5-DMF. The cat- alysts were broadly characterized by different techniques, such as XRD, N2-isotherms, XPS, TPR, TEM and NH3- TPD. It was found that the metallic particles were well reduced and highly dispersed on the surface of supports having large surface area and narrow pore size distribution. The PtIr alloy species catalytic sites were very active and selective towards the formation of the desired 2,5-DMF. PtIr-CMK-3 catalyst showed an excellent activity, selectivity and stability to be applied in this process.
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    Indole HDN using iridium nanoparticles supported on titanium nanotubes
    (2022) Ledesma, Brenda Cecilia; Martínez, María Laura; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel
    The HDN of indole was studied over iridium modified titanate nanotube catalyst. Titanium nanotube was prepared by the alkaline hydrothermal method. Iridium was added by wetness impregnation. The activity was compared with Ir–TiO2 and commercial NiMo/Al2O3 catalysts. The catalysts prepared were characterized by X-ray diffraction (XRD), N2 adsorption isotherms, UV–Vis-DRS, FTIR, XPS, TEM, Py-FTIR and H2-Chemisorption. XRD, N2 isotherms and UV–vis-DRS con- firmed the nanotube structure. The analysis showed that the mesoporous structure was maintained after Ir incorporation. The results showed that titanate nanotube as support significantly reduce the size of iridium crystallites and improves its dispersion considerably. Iridium titanate nanotube presented abundant and strong Brönsted acidity compared with TiO2 iridium catalyst. According a kinetic study, Ir–TNT was the most active catalyst for indole HDN, in mild conditions in a Batch reactor. The Brönsted acidity in synergic effect with Lewis acidity and hydrogenolysis capacity of iridium species were the responsible for the good activity.
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    Influence of ti incorporation to bimetallic mesoporous carbon in the production of 2,5‑dimethylfuran from biomass derivatives
    (2021) Ledesma, Brenda Cecilia; Juárez, Juliana María; Domine, Marcelo E.; Beltramone, Andrea Raquel
    Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done to understand structure–activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetal- lic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.