Facultad Regional Rosario

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Author: search.filters.author.Mores, Patricia LilianaSubject: search.filters.subject.CO2 capture

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    Cost-based comparison between membrane systems and chemical absorption processes for CO2 capture from flue gas.
    (2019-05-09) Arias, Ana Marisa; Mores, Patricia Liliana; Scenna, Nicolás José; Caballero, José Antonio; Mussati, Miguel Ceferino; Mussati, Sergio Fabián
    An optimization study of membrane-based separation systems for carbon dioxide capture from flue gas of power plants is conducted, considering the possibility of employing up to four stages and using diverse options to create the required driving force. By proposing a superstructure-based model, the number of stages, recycle options, use of feed compression and/or permeate vacuum, driving force distribution along each membrane stage, operating conditions and equipment sizes are simultaneously optimized in order to minimize the total annual cost at high capture ratios and purity targets. Thus, different optimal arrangements are obtained and the total cost is reduced in about 20% compared without employing vacuum. Besides the optimal number of stages diminishes with decreasing purity, but it is independent of the capture ratio. Also, the total cost decreases with the increase of the membrane permeance requiring lower values of operating pressure and membrane areas. Permeance values higher than 2400 GPU lead to lower number of stages and recycles for the same separation target. By contrast, a sensitivity analysis shows that the total cost increases with the increase of the electricity price, capacity factor, and capital recovery factor, which are the more influential parameters in the objective function. Despite new optimal operating and design conditions are obtained when these parameters vary, no modifications in the optimal arrangement are observed.
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    Water influence on total annual cost for CO2 separation through a two-stage membrane system.
    (Asociación Argentina de Ingenieros Químicos/ Oscar Pagola, 2023-06) Arias, Ana Marisa; Kraft, Romina Alejandra; Scenna, Nicolás José; Mores, Patricia Liliana
    Carbon capture remains as one of the most promising alternatives to mitigate flue gas impact from installed plants. Several alternatives are being studied with different development levels. Membranes have been employed for gas separation in diverse industries; its application for carbon capture has been largely discussed. The mayor drawback of this technology lies on the high-energy requirement for driving force generation and its liability when treating humid gas. As a first approach to CO2 separation, early works study binary gas mixtures as representative of flue gases. However, the presence of a little amount of H2O may affect the separation in ways that need to be explored. In this work, an analysis on the impact of H2O presence on the driving force and overall separation efficiency is carried out. A four- component flue gas mixture including H2O and 02 is considered for a more realistic approach. The process objective is to recover 90% of the incoming CO2 and deliver a high purity permeate. Here, a typical two-stage counter-current membrane system is studied (Figure 1). Each stage includes a feed compressor followed by a cooler, the first one is also connected to a vacuum pump on the permeate side and another cooler. An optimization program based on a previous model [1] modified to consider a four-component mixture is implemented in GAMS. Mass and energy transfer phenomena, investment and operative costs, among others, are represented by a set of algebraic equations. Three different driving force generation setups are considered: feed compression, permeate vacuum, or a combination of both. Total annual cost (TAC) is selected as objective function to assess all the trade-offs between investment and operative costs, contrasting and accounting H2O influence. The resulting optimal driving force generation strategy includes a combination of feed compression and permeate vacuum pumping, fulfilling a 90% CO2 recovery. In fact, the incidence of investment over TAC is much less pronounced than the costs related to energy consumption.