Experimental Desing Optimization of the ODS of DBT using V2O5 supported on Ga-SBA-15.
dc.creator | Rivoira , Lorena Paola | |
dc.creator | Cussa , jorgelina | |
dc.creator | Martínez , María Laura | |
dc.creator | Beltramone , Andrea Raquel | |
dc.creator | Martínez , María Laura | |
dc.creator | Cussa , jorgelina | |
dc.date.accessioned | 2025-03-27T21:59:46Z | |
dc.date.issued | 2020 | |
dc.description.abstract | Experiment design-response surface methodology (RSM) was used in this work to model and optimize one response in the oxidative desulfurization of dibenzothiophene with hydrogen peroxide using VOx-Ga-SBA-15 catalysts with different Ga/Si and V/Si ratios. In this study, we analyze the influence of the nature of the catalyst (metal/Si ratio), the catalyst/substrate ratio and the oxidant/substrate ratio as factors for the design. The response analyzed was conversion at 15 min of reaction time. The response surfaces were obtained with the Box–Behnken Design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the objective function were obtained employing the catalyst with Ga/Si and V/Si ratios of v1/15 and 1/25, respectively. Structural and textural characterization of the catalysts were performed by means of XRD, N2 adsorption, UV–Vis–DRS, XPS, NMR, TEM, Raman, TPR and Py-FTIR. UV–Vis–DRS and Raman demonstrated that highly dispersed vanadium pentoxide crystallites are responsible for the high activity in the sulfur removal. The high dispersion depended on the vanadium loading and on the nature of the support. | |
dc.description.affiliation | Fil: Rivoira, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina. | |
dc.description.affiliation | Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina. | |
dc.description.affiliation | Fil: Martínez, María Laura. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina. | |
dc.description.affiliation | Fil: Beltramone, Andrea Raquel . Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina. | |
dc.format | ||
dc.identifier.citation | XXV International Materials Research Congress. | |
dc.identifier.uri | https://hdl.handle.net/20.500.12272/12538 | |
dc.language.iso | en | |
dc.publisher | Univesidsad Tecnológica Nacional. | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | en |
dc.rights.holder | Rivoira, Lorena Paola; Cussa, Jorgelina; Martínez, María Laura; Beltramone, Andrea Raquel. | |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.rights.use | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | ODS | |
dc.subject | DBT | |
dc.subject | V2O5 | |
dc.subject | Ga-SBA-15 | |
dc.subject | ODS DBT | |
dc.title | Experimental Desing Optimization of the ODS of DBT using V2O5 supported on Ga-SBA-15. | |
dc.type | info:eu-repo/semantics/article | |
dc.type.version | acceptedVersion |
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