Direct Synthesis of ordered mesoporous carbon as support of Ir-Catalyst and its application in hydrodenitrogenation of indole.

dc.creatorLedesma, Brenda Cecilia
dc.creatorJuárez , Juliana María
dc.creatorBeltramone, Andrea Raquel
dc.creatorJuárez , Juliana María
dc.date.accessioned2025-03-27T18:49:14Z
dc.date.issued2018
dc.description.abstractAn ordered mesoporous carbon (OMC) modified with titania was prepared using a novel and shorter synthesis method. OMC was successfully synthesized by the carbonization of the silica/TEOT/triblock copolymer/sucrose composite in the presence of sulfuric acid. This novel material was modified with the incorporation of nanoparticles of Iridium. Structural and textural characterization of the catalyst was performed by means of N2 adsorption, XRD, UV–Vis–DRS, Raman spectroscopy, XPS, TEM and H2 Chemisorption. The characterization results indicated that the textural and structural properties of the support synthesized by the short time method are comparable with the properties of the support prepared by the hard template method. Ir-Ti-OMC catalyst obtained by short time synthesis was active and selective in the hydrogenation of indole. Main advantage of the present study is the reduction of time and cost in the synthesis of the new material and the applicability for HDT reactions.
dc.description.affiliationFil: Ledesma, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.formatpdf
dc.identifier.citation2nd International Conference on Catalysis and Chemical Engineering.
dc.identifier.urihttps://hdl.handle.net/20.500.12272/12521
dc.language.isoen
dc.publisherUnivesidsad Tecnológica Nacional.
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.holderLedesma, Brenda Cecilia; Juárez, Juliana María; Beltramone, Andrea Raquel.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.usehttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectSynthesis
dc.subjectMesoporous carbon
dc.subjectIr-Catalist
dc.titleDirect Synthesis of ordered mesoporous carbon as support of Ir-Catalyst and its application in hydrodenitrogenation of indole.
dc.typeinfo:eu-repo/semantics/article
dc.type.versionacceptedVersion

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