HDN of indole over Ir-modified Ti-SBA-15.

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dc.creatorLedesma , Brenda Cecilia
dc.creatorAnunziata, Oscar Alfredo
dc.creatorBeltramone , Andrea Raquel
dc.date.accessioned2025-06-27T18:43:49Z
dc.date.issued2017
dc.description.abstractIridium catalyst was prepared using a novel tita nium oxide-CMK-3 support synthesized as a replica of Ti SBA-15. The catalyst was applied in the hydrodenitrogena tion of indole. The activity was compared with an iridium catalyst supported over a grafted titanium-CMK-3. Struc tural and textural characterization of the catalysts was per formed by means of N2 adsorption, XRD, UV–Vis–D Raman spectroscopy, XPS, TEM and H2 Chemisorption. Ir-Ti-CMK-3 was the most active catalyst for the hydro denitrogenation reaction at mild conditions. Titanium oxide contained in carbon ordered mesoporous CMK-3 promotes a very good anchorage of iridium metallic clusters in the carbon framework reaching high active site distribution and more stable nanoclusters.
dc.description.affiliationFil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.formatpdf
dc.identifier.citationElsevier- Applied Catalysis B: Environmental journal homepage.
dc.identifier.urihttps://hdl.handle.net/20.500.12272/13366
dc.language.isoen
dc.publisherUniversidad Tecnológica Nacional Regional Córdoba.
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.holderLedesma, brenda;Beltramone Andrea Raquel; Anunziata Oscar Alfredo.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.usehttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectHydrodenitrogenation
dc.subjectTitanium
dc.subjectMesoporous
dc.subjectIridium crystallites
dc.subjectKinetica
dc.titleHDN of indole over Ir-modified Ti-SBA-15.
dc.typeinfo:eu-repo/semantics/article
dc.type.versionacceptedVersion

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