Experimental Desing Optimization of the tetralin Hydrogenation over Ir-Pt-SBA-15.

dc.creatorVallés , Verónica Alejandra
dc.creatorLedesma, Brenda Cecilia
dc.creatorRivoira , Lorena Paola
dc.creatorCussa , jorgelina
dc.creatorAnunziata , Oscar Alfredo
dc.creatorBeltramone, Andrea Raquel
dc.creatorAnunziata , Oscar Alfredo
dc.creatorCussa , jorgelina
dc.creatorRivoira , Lorena Paola
dc.creatorLedesma, Brenda
dc.date.accessioned2025-03-21T20:25:56Z
dc.date.issued2016
dc.description.abstractExperiment design-response surface methodology (RSM) is used in this work to model and optimize two responses in the hydrogenation of tetralin to decalin using bimetallic Ir–Pt-SBA-15 catalyst. In this study, we analyze the influence of the nature of the catalyst (metal molar fraction and metal loading), the catalyst/substrate ratio and the temperature of the reaction as factors for the design. The responses analyzed were conversion at 3 h and at 5 h of reaction time. The response surfaces were obtained with the Box–Behnken design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the two objective functions were obtained employing the catalyst with 1 wt.% of iridium and 0.7–0.8 wt.% of platinum; the optimal ratio between mass of catalyst and mole of tetralin was 17–19 g/mol and temperature between 200 and 220 ◦C.
dc.description.affiliationFil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Rivoira, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Beltramone, Andrea Raquel . Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.formatpdf
dc.identifier.citationCatalysis today 271 2016.
dc.identifier.urihttps://hdl.handle.net/20.500.12272/12461
dc.language.isoen
dc.publisherUnivesidsad Tecnológica Nacional
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.holderVallés, Verónica Alejandra; Ledesma, Brenda Cecilia; Rivoira, Lorena Paola; Cussa, Jorgelina; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.usehttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectIridium-Platinum containing SBA-15
dc.subjectTetralin hydrogenation
dc.subjectTrans/cis ratio
dc.subjectExperimental desing
dc.titleExperimental Desing Optimization of the tetralin Hydrogenation over Ir-Pt-SBA-15.
dc.typeinfo:eu-repo/semantics/article
dc.type.versionacceptedVersion

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