Influence of Ti Incorporationto Bimetallic Mesoporous Carbon in the Production of 2,5-Dimethylfuran from Biomass Derivatives.

dc.creatorLedesma , Brenda Cecilia
dc.creatorJuárez , Juliana María
dc.creatorDomine , Marcelo
dc.creatorBeltramone, Andrea Raquel
dc.creatorBeltramone, Andrea Raquel
dc.creatorJuárez , Juliana María
dc.date.accessioned2025-06-26T20:12:43Z
dc.date.issued2021
dc.description.abstractMonometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done to understand structure–activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetal lic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
dc.description.affiliationFil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.description.affiliationFil: Domine, Marcelo. Universidad Politécnica de Valéncia. Instituto de Tecnología Química; España.
dc.description.affiliationFil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
dc.formatpdf
dc.identifier.citationCatalysis Letters
dc.identifier.urihttps://doi.org/10.1007/s10562-021-03711-8
dc.identifier.urihttps://hdl.handle.net/20.500.12272/13334
dc.language.isoen
dc.publisherUniversidad Tecnológica Nacional.
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.holderLedesma, Brenda Cecilia; Juárez, Juliana María; Domine, Marcelo; Beltramone, Andrea Raquel.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.usehttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectTitanium
dc.subjectPlatinum
dc.subjectIridium
dc.subjectModified mesoporous carbon
dc.subject5-hydroximethylfurfural
dc.subject2,5-dimethylfuran
dc.titleInfluence of Ti Incorporationto Bimetallic Mesoporous Carbon in the Production of 2,5-Dimethylfuran from Biomass Derivatives.
dc.typeinfo:eu-repo/semantics/article
dc.type.versionacceptedVersion

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
2244.- Influence of Ti Incorporation to Bimetallic Mesoporous Carbon in the Production of 2,5‑Dimethylfuran from Biomass Derivatives.pdf
Size:
310.23 KB
Format:
Adobe Portable Document Format

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
3.63 KB
Format:
Item-specific license agreed upon to submission
Description: